#74 - April 2001
New Technology - Meat Products

Is There a Future for Yellow Grease, Tallow, as a Premium Diesel Fuel Blending Stock?

By Alex Spataru, The Adept Group, Inc. Contact Adept Group

  • In 2000, yellow grease (YG) prices reached a 30-year low and North American exports were down. Currently, some U.S. renderers are burning YG in their boilers instead of diesel, fuel oil, or natural gas. In air pollution sensitive areas, YG cannot be burned in boilers, and in many areas where burning YG is allowed, such authorization may be revoked. The production and sale of biodiesel fromYG appears to be just a temporary solution that is dependent on various government subsidies for economically viability. The use of biodiesel in modern compression ignited engines (other than as a lubricity additive) may also run into air quality regulatory obstacles. Renderers need to continually look for new and dependable YG market outlets.

  • Scientists at the CANMET Energy Technology Centre (CANMET) in Ontario, Canada, have proven at lab scale a process to convert YG and/or tallow and/or poultry fat into a valuable low-sulfur, high cetane premium diesel blending stock. The process used is based on a refining technology called hydrotreating. Figure 1 describes the necessary equipment and the material flows. The principal output is a diesel blending stock called AGTANE (for AGricultural ceTANE) in English speaking countries (e.g. Australia, United Kingdom, United States, etc.), and BIOZOLE in French speaking countries.

  • Figure 1: AGTANE Process



    • Several convergent global trends favor AGTANE production from YG. Diesel prices have risen and they are expected to remain high. There is also increased regulatory pressure towards the increased use of diesels and biodiesels with low sulfur content and reduced particulate matter emissions. Such “clean diesels” are significantly more expensive than the diesels commonly used over the last decade.
    • AGTANE could provide to the rendering industry steady and continuous global outlets for sizeable YG sales (increasing and maintaining “product disappearance”) while establishing a new and reliable customer base (e.g., the petroleum refining industry). The potential to create a permanent pricing floor for YG and tallow across the world also exists.
    • For the rendering industry, the production of AGTANE in sufficiently large quantities presents an effective means to help keep YG prices from falling below a minimum threshold (approximately $0.09/lb.).
    • Based on its bottom line appeal, AGTANE production is expected to be readily implemented in major urban areas where large rendering operations are located within 50 miles of petroleum refining facilities.


    What is AGTANE?

  • AGTANE, a collection of long-chained paraffins, is a premium diesel blending stock. AGTANE is not a biodiesel (biodiesels are esters).
  • Conservative economic models indicate that for mass production plants (>750,000 gallons/year), YG can be profitably converted to AGTANE. Three economic models were prepared for AGTANE production. The renderer-only model is shown in Figure 2.

  • Figure 2: Renderer-Only Plant Model


    - AGTANE production and sales make sense due to improved engine performance, in place zero- or low-cost product distribution, and because it offers only environmental benefits (no trade-offs). Some of these considerations are discussed below.
    (1) Engine Performance Considerations
  • AGTANE blended diesel will not require fuel suppliers to increase the use (and cost) of algae and/or bacteria killers. Biodiesel blends typically require more algae and/or bacteria-killing additives than regular diesels.
  • Being a collection of long-chain paraffins, AGTANE has a field tank storage life equal to or superior to currently commercialized diesel fuels. Diesel engines were designed to burn fuels that include paraffins, which are normally found in commercial diesel fuels. Biodiesels are unkind to modern fuel injection systems.
  • AGTANE has been repeatedly shown to have cetane values of over 100, before blending, and have excellent physical and chemical characteristics that make it an ideal blending stock. Typically, biodiesels have cetane values between 50 and 60. Table 1 compares AGTANE with California Air Resources Board (CARB) specified diesels.
  • Table 1


    (2) Product Distribution Considerations
    AGTANE will be distributed through existing refined petroleum products distribution channels. Refiners exposed to AGTANE consider it to be a “synthetic diesel.” California refiners have indicated they would buy the product once it becomes commercially available. Some California refiners currently buy a similar (although not as high quality) low sulfur diesel blending stock from Malaysia. The same refiners have indicated that they would support an AGTANE demonstration project once a small pilot plant has been field proven.

    (3) Environmental Considerations
    Unlike biodiesel, there are no engine emission trade-offs. No water is needed to produce AGTANE (water is needed to make biodiesel). On the BSE front, prions are destroyed due to intense heat and high pressures in making AGTANE. It is likely that prions may survive the biodiesel manufacturing process due to lower heat and pressures conditions.

    (4) Bottom-Line Considerations
    - AGTANE quality is not affected by the YG’s free fatty acid (FFA) content. Biodiesel production is severely affected by FFA content of the raw materials.
    - A by-product of AGTANE production is a low-sulfur, heavy oil cut that is readily marketable or that can serve as source material for hydrogen (necessary to make AGTANE). The entire AGTANE manufacturing process can ultimately be made H2 self-sufficient.


    Production Potential
    It is thought that annual production of AGTANE in the North America could readily exceed 570 million gallons. In California alone, about 51 million gallons of this product can be steadily produced each month, replacing an equivalent amount of petroleum derived diesel.

    Figure 3. Impact of Yellow Grease-derived AGTANE on Diesel Cetane Number


    - CANMET recently commissioned research that proved synergy between AGTANE and traditional cetane improvers, thus increasing its value. Baker Commodities (Baker) in Los Angeles, CA, contributed YG and Tosco Oil (Tosco) provided CARB unadditized diesel to Ottawa. CANMET made AGTANE from YG and blended specified amounts with Tosco unadditized diesel. Cetane tests were conducted by Advanced Engine Technology, Ltd. (AET). The “traditional” cetane improver used by AET was Octel CI-0801.

    Figure 4: Response of Tosco Diesel Fuel to Commercial Cetane Improver


    - Figure 3 shows how AGTANE linearly enhances the cetane value of an unadditized blend while Figure 4 shows how a traditional cetane improver effects eventually flattens out. The test results indicated that AGTANE:
    1. Linearly raised the cetane of unadditized Tosco diesel without a top-end limit(#1);
    2. Can linearly raise the cetane of “non-responsive”(#2) diesel blends;
    3. Is synergistic with traditional cetane improvers;
    4. Has a low sulfur content (~15 ± 5ppm)(#3);
    5. Increases end-product volume by the added AGTANE volume;
    6. Can finish the refining process for an unadditized diesel at a lower cetane value than previously possible; and
    7. Allows diesel blenders/traders to buy and profitably resell lower cetane “non-responsive” diesel stock.

    The ADEPT Group, Inc. (ADEPT) is currently organizing a consortium to fund further research and development of the AGTANE technology. The intent is to make this technology available worldwide.
    For further information, please Contact Adept Group

    #1 The cetane value enhancing effects of traditional cetane improvers level off at some point, after an eight or nine point rise in cetane value.
    #2 “Non-responsive” means that certain diesel stocks turn out not to respond well to increasing cetane value when traditional cetane additives are mixed in.
    #3 15-ppm max. S2 in on-road diesel is a South Coast Air Quality Management District requirement by 2005.


Author :MHR Viandes
Date updated :23/05/01
Number of words :0

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